1.
Org Lett
; 13(4): 576-9, 2011 Feb 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21244043
RESUMO
The use of manganese(III) acetate allows the direct synthesis of diverse arrays of [4.3.0] bicyclic carbohydrate-based γ-lactone building blocks from glycals. A mechanism to explain the high regio- and stereoselectivity is proposed. The new reaction has the potential to generate libraries for biological screening.